1 AIT Asian Institute of Technology

Chloride and potassium distribution in modern kraft recovery boiler

AuthorSarawut Jetinai
Call NumberAIT Thesis no. PP-99-14
Subject(s)Kraft paper industry

NoteA thesis submitted in partial fulfillment of the requirements for the degree of Master of Engineering, School of Environment, Resources and Development
PublisherAsian Institute of Technology
AbstractThe study was set up to investigate the influence of electrostatic precipitator (ESP) ash on the distribution of chloride and potassium in modern kraft recovery boiler. Both chloride and potassium, which enter a mill with wood raw material, lower the melting point of fume or ash, causing deposits and plugging the flue gas passage, and also accelerating corrosion. Advance Agro Public Company Limited, the first pulp and paper integrated mill in Thailand has conducted the study. Under the variation in two set of conditions: ESP ash recycling and removing, the elements in concern such as sodium, potassium and chloride presented in black liquor, smelt and ESP dust were quantified as well as sulfate in black liquor and flue gas. Both the chloride and potassium contents in black liquor solids of 1.5% and 5.1 %(wt), respectively, in condition of ESP ash recycling considered as normal operation, are higher than the typical values of about 3 times. The predicted sticky temperature of ESP dust is about 520°C corresponding to chloride and potassium enrichments in the dust both of around 20% mole. With operating superheated steam temperature of about 450 °C, plugging is likely occmred. Chloride and potassium enrichment factors of ESP dust are 4.7 and 1.5, showing less variation to the typical values of around 3 and 1.6, respectively. Chloride and potassium enrichment of 20.0% and 20.2% mole in case of ESP ash recycling show insignificant difference to that of ESP ash removing of 18.3% and 18.4% mole, respectively. To the lower extent of chloride and potassium enrichments, ESP ash disposing period is required long run up to month. The mill situation contains relatively high level of chloride and potassium, but not critically high.
Year1999
TypeThesis
SchoolSchool of Environment, Resources, and Development (SERD)
DepartmentDepartment of Food, Agriculture and Natural Resources (Former title: Department of Food Agriculture, and BioResources (DFAB))
Academic Program/FoSPulp and Paper Technology (PP)
Chairperson(s)Malinen, Raimo 0.;
Examination Committee(s)Kiiskila, Erkki ;Kolehmainen, Heikki;
Scholarship Donor(s)Advance Agro Public Company Limited;
DegreeThesis (M.Eng.) - Asian Institute of Technology, 1999


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