1 AIT Asian Institute of Technology

Lignin removal from pulping process wastewater by ultrafiltration

AuthorNilapha Paemanee
Call NumberAIT Thesis no. EV-97-28
Subject(s)Sewage--Purification--Microstraining
NoteA thesis submitted in partial fulfillment of the requirements for the degree of Master of Science, School of Environment, Resources and Development
PublisherAsian Institute of Technology
Series StatementThesis ; no. EV-97-28
AbstractThe efficiencies of four type ultrafiltration membrane, fluoro polymer (FS) of MWCO 20,000 and 10,000 dalton and polysulphone (GR) of MWCO 10,000 and 5,000 dalton were used for the removal of lignin which has a wide range of molecular weight and are main reason to make a high COD and color in wastewater from pulping process. The efficiency of lignin separation using four different ultrafiltration membranes, namely fluoro polymer (FS) of MWCO 20,000 and 10,000 dalton and Polysulphone (GR) of MWCO 10,000 and 5,000 were experimentally studies. The raw wastewater contain lignin was obtained from three different pulping processes; black liquor, chlorine bleaching, and caustic extraction (EOP bleaching). The experimental runs were conducted within a temperature range of 40-60°C and transmembrane pressure were varied from 5. 0 -3. 0 bar for FS61 while the transmembrane were reduced from 4.0-2.5 bar for others. It indicated that besides the higher transmembrane pressure resulted higher contaminants removal efficiencies such as COD, TDS, Color and Lignin, the potential of ultrafiltration membrane to remove contaminants were affected by membrane molecular weight cut off and type of ultrafiltration membrane. High MWCO ultrafiltration membrane resulted in low contaminant removal efficiency and FS has higher removal efficiency than GR, but were independent of the operating temperature from 40°, to 60°C range. Ultrafiltration of black liquor resulted in moderate removals of COD about 25-65%, depending in transmembrane pressure and MWCO of ultrafiltration membrane whereas it has a good removal efficiencies of Lignin and Color about 40-80 %. COD removal of Ch and EOP bleaching wastewater were 20-60%. Removal of Color and Lignin of EOP bleaching wastewater were 30-60% while resulted in poor removal of Color and Lignin of Ch bleaching wastewater (10-45%). However, ultrafiltration of all pulping wastewater streams used has poor removal ofTDS (10-40%).
Year1997
Corresponding Series Added EntryAsian Institute of Technology. Thesis ; no. EV-97-28
TypeThesis
SchoolSchool of Environment, Resources, and Development (SERD)
DepartmentOther Field of Studies (No Department)
Academic Program/FoSEnvironmental Engineering (EV)
Chairperson(s)Visvanathan, C.
Examination Committee(s)Annachhatre, Ajit P.;Malinen, Raimo O.
Scholarship Donor(s)Electricity Generating Authority of Thailand (EGAT)
DegreeThesis (M.Sc.) - Asian Institute of Technology, 1997


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