1 AIT Asian Institute of Technology

Removal of heavy metals using chitosan

AuthorNaing Naing Win
Call NumberAIT Thesis no.EV-96-21
Subject(s)Sewage--Purification--Heavy metals removal

NoteA thesis submitted in partial fulfillment of the requirements for the degree of Master of Science
PublisherAsian Institute of Technology
AbstractCopper and chromium removal capacities of chitosan were studied using batch and continuous column experiments. Kinetics and isotherm studies indicated that heavy metals such as chromium and copper can be effectively removed by chitosan. The rates of sorption were very rapid initially. At low equilibrium concentration, maximum adsorption were obtained within 4 and I hour for copper and chromium respectively. 13 mg copper and 16.5 mg chromium could be adsorbed per gram of chitosan at an equilibrium heavy metal concentration of 1mg/L. Effect of operating parameters such as pH, chloride ion, complexing agents such as ethylenediamine tetraacetate (EDT A), particle size and coions on chitosan heavy metal removal capacity were investigated. Copper and chromium adsorption were maximum at pH value of 6.0 and 3.0 respectively. Presence of chloride ion did not improve adsorption of copper but chromium uptake was significantly reduced. Soluble complexing agents such as ethylenediamine tetraacetate (EDT A) decreased the sorption of copper and chromium. Smaller chitosan particles have higher metal adsorption capacity. Presence of coions also increased metal adsorption capacity of chitosan. Used chitosan was regenerated with acid and base for copper and chromium respectively and reused. Results from this study indicated that chitosan adsorption for copper and chromium removal can have practical applications in water and wastewater treatment processes.
Year1996
TypeThesis
SchoolSchool of Environment, Resources, and Development (SERD)
DepartmentDepartment of Energy and Climate Change (Former title: Department of Energy, Environment, and Climate Change (DEECC))
Academic Program/FoSEnvironmental Engineering and Management (EV)
Chairperson(s)Annachhatre, Ajit P.;
Examination Committee(s)Stevens, Willem Frans;Suwalee Chandrkrachang;Kamei, Tasuku;
Scholarship Donor(s)Asian Institute of Technology;
DegreeThesis (M.Sc.) - Asian Institute of Technology, 1996


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