1 AIT Asian Institute of Technology

Effects of molybdate addition on the anaerobic treatment of sulfate-rich wastewater

AuthorLee, Young Ho
Call NumberAIT Thesis no.EV-93-35
Subject(s)Sewage--Purification--Biological treatment

NoteA thesis submitted in partial fulfillment of the requirement for the degree of Master of Engineering
PublisherAsian Institute of Technology
AbstractThe anaerobic treatment of amino acid wastewater with the addition of molybdate was studied using upflow anaerobic filter reactors. The batch test was conducted to obtain the optimum concentration of molybdate for application to the anaerobic filter reactor. Higher methane production and complete inhibition of sulfate reduction were observed at 3 mM molybdate. Four laboratory scale upflow anaerobic filter with the total volume of 16.81 was used. The amino acid wastewater which contained Sg COD/l and 3g sulfate/I was used as the substrate. In the initial stage of phase I, no molybdate was added to the reactors for the period of 61 days. Then the reactors were fed with 4 different concentration of molybdate (l, 3, 5 and 10 mM). The complete inhibition of sulfate reduction was observed when the molybdate concentration was 3, 5 and 10 mM. Increasing methane production was observed only when the molybdate concentration was 3mM. But when the molybdate concentration was 5 or 10 mM, both methanogenesis and sulfate reducing bacteria were inhibited. The recovery of methane production was difficult after methanogenesis inhibition. In phase II, molybdate(3mM) was added at the time of start-up of the reactor to discourage the growth and development of sulfate reducing communities. Methane production of the continuous addition of molybdate(3mM) was better than that of the intermittent addition of 3mM (at a two day interval). Methane production was improved 5.3 times more than that of the control with the inhibition of sulfate reduction (72.7%). COD removal was not largely affected with or without the addition of molybdate in organic loading rates of 2.4 and 1.2 kg COD/m3.day with upflow anaerobic filter reactors.
Year1993
TypeThesis
SchoolSchool of Environment, Resources, and Development (SERD)
DepartmentDepartment of Energy and Climate Change (Former title: Department of Energy, Environment, and Climate Change (DEECC))
Academic Program/FoSEnvironmental Engineering and Management (EV)
Chairperson(s)Tanaka, Shuzo;
Examination Committee(s)Lee, Seong-Key;Samorn Muttamara;
Scholarship Donor(s)Government of Korea;
DegreeThesis (M.Eng.) - Asian Institute of Technology, 1993


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