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Energy consideration of ozone generation and reactivity of ozone with selected media | |
Author | Qadeer, Ejaz |
Call Number | AIT Thesis no. ET-91-4 |
Subject(s) | Ozone |
Note | A thesis submitted in partial fulfillment of the requirement for the degree of Master of Engineering, School of Environment, Resources and Development |
Publisher | Asian Institute of Technology |
Abstract | The study deals with the validation of some assumptions regarding the existence of excited ozone. In the theoretical development, various possibilities have been checked by using the concepts of thermodynamics and engineering leading to the conclusion that a mixture of various levels of ozone is most probably generated in an ozonizer depending on the prevailing conditions in it. Theoretical consideration have been experimentally supported by generating ozone under different conditions, i.e. high voltage with dilution and low voltage without dilution. Reactivity of these ozones have been tested in various media and found to be in agreement with the theoretical consideration Ozonation of oxalic acid has been tried, resulting in the conclusion that the mechanism of activation of ozone by UV in liquid phase could differ from those in gasous phase or ozone in liquid phase reacts with species such as OH, these are the species excited by UV and not directly by ozone. The experiments also support previous investigations such as bleaching of ozone in acidic media, underactivity of ozone with oxalic acid, and the reaction of oxalic acid with ozone in the presence of UV. This study provides the most probable explanation for such. |
Year | 1991 |
Type | Thesis |
School | School of Environment, Resources, and Development (SERD) |
Department | Other Field of Studies (No Department) |
Academic Program/FoS | Energy Technology (ET) |
Chairperson(s) | Mora, Jean-Claude |
Examination Committee(s) | Mohanty, B. ;Bo, Khin |
Scholarship Donor(s) | Government of France |
Degree | Thesis (M.Eng.) - Asian Institute of Technology, 1991 |