1 AIT Asian Institute of Technology

Kinetics of organic carbon and nitrogen removal in attached-growth circulating reactor

AuthorSeni Karnchanawong
Call NumberAIT Diss. no. EV-89-03
Subject(s)Sewage--Purification--Nitrogen removal

NoteA dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Engineering
PublisherAsian Institute of Technology
AbstractExperiments on attached-growth circulating reactor (AGCR) were conducted to investigate its efficiencies on organic carbon and nitrogen removal (through denitrification). A laboratory-scale AGCR, made of serpentine channel with the dimensions of 0.05 x 0.20 x 180.00 m (width x depth x length), was fed with synthetic wastewater at the chemical oxygen demand (COD) and total nitrogen (TN) loading rates of 3.6-10.2 and 0.30-0.91 g/(m2 .d), respectively. The reactor effluent was recycled back to the influent feeding point and the dissolved oxygen (DO) concentrations along the channel length were controlled by means of air diffusion. It was found that the COD loading rate of 5 g/ (m2.d) corresponding to the TN loading rate of 0. 54 g/ (m2. d) gave the optimum COD and TN removal rates of 4.8 and 0.43 g/(m2 .d), respectively. The overall AGCR performance was limited by the nitrification efficiency at the high TN loading rates. The biofilm accumulation and thickness were found to be distinctly higher in the first-half portion than the second-half portion of the channel length. A pilot-scale AGCR with the dimensions of 0.30 x 1.00 x 62.25 m (width x depth x length) was operated at the COD and TN loading rates of 3.9-6.1 and 0.59-0.93 g/(m2 .d), respectively, using campus sewage as an influent feed. For removal of settleable solids, the AGCR effluent was partially directed to a square sedimentation tank with the dimensions of 0. 50 x 0. 50 x 0. 70 m (width x length x depth). It was found that the overall TN removal efficiency was limited by denitrification because there was no DO sag-curve profile occurring during the pilot-scale experiments. The COD loading rate of 4.6 g/(m2 .d) corresponding to the TN loading rate of 0. 69 g/(m2•d) gave the optimum COD and TN removal rates (at the effluent of the sedimentation tank) of 3.8 and 0.45 g/(m2.d), respectively. The biofilm accumulation and thickness did not significantly vary along the channel length. Batch experiments were conducted under suspended conditions to determine the maximum substrate utilization rates (k) of the biofilms. It was found that the k values varied along the AGCR laboratory-scale channel length according to the DO concentration profile and the predominant biochemical reactions. The similar trends of k values variation were observed in the pilot-scale unit, but the extent of variation was not so large as that of the laboratory-scale unit. A mathematical model was proposed to include and simulate all three biofilm reactions (carbon oxidation, nitrification, denitrification) along the channel length. It was found that for the laboratory-scale AGCR unit operated at low COD and TN loading rates, DO concentration was the limiting factor for carbon oxidation and nitrification in the first-half portion, and biofilm thickness was the limiting factor for the second-half portion of the channel length (where denitrification did not exist). For the pilot-scale and laboratory-scale AGCR (operating at high loading rates), denitrification occurred throughout the channel length and DO concentration was the limiting factor for carbon oxidation and nitrification activites.
Year1989
TypeDissertation
SchoolSchool of Environment, Resources, and Development (SERD)
DepartmentDepartment of Energy and Climate Change (Former title: Department of Energy, Environment, and Climate Change (DEECC))
Academic Program/FoSEnvironmental Engineering and Management (EV)
Chairperson(s)Chongrak Polprasert;
Examination Committee(s)Vigneswaran, S.;Verink, Johan;Huynh, Ngoc Phien;Harremoes, Poul;
Scholarship Donor(s)Royal Norwegian Government;
DegreeThesis (Ph.D.) - Asian Institute of Technology, 1989


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